Arsenal have won all five games to sit top of the standings
Three points is the gap between Paris Saint-Germain in second and 14th-placed Galatasaray
Ajax are bottom of the pile with no points from five matches
The last round of Champions League fixtures for 2025 takes place this week and Arsenal will be hoping to extend their perfect record in the League Phase.
Kairat vs Olampiakos (Tuesday, 3.30pm)
Both teams are still seeking their first win of this season’s tournament and that will be the main target, with qualification looking unlikely.
Home advantage could be key and a stubborn Kairat side kept a clean sheet in their previous European home tie.
Score Prediction: Kairat 1-0 Olympiakos
Bayern Munich vs Sporting (Tuesday, 5:45pm)
Sporting are the surprise package of the tournament so far, with the Portuguese side inside the top eight after three victories in their first five games.
A trip to Bayern Munich is a big step up though, with Vincent Kompany’s men losing just one home game all year - that was a Bundesliga defeat to Bochum in March.
Score Prediction: Bayern Munich 3-1 Sporting
Atalanta vs Chelsea (Tuesday, 8pm)
Atalanta have been the draw specialists this season, with seven of their 14 Serie A matches finishing all square.
Chelsea head to Bergamo off the back of a draw at Bournemouth, with a point on Tuesday keeping them ahead of their opponents.
Score Prediction: Atalanta 1-1 Chelsea
Barcelona vs Eintracht Frankfurt (Tuesday, 8pm)
Barcelona find themselves down in 18th going into Game Six, after two defeats and one draw in their first five matches.
The LaLiga leaders face an Eintracht Frankfurt team who have not won in Europe since their opening success over Galatasaray.
Score Prediction: Barcelona 4-1 Eintracht Frankfurt
Inter Milan vs Liverpool (Tuesday, 8pm)
Serie A leaders Inter have five wins in their last six in the league and are currently sat fourth in the Champions League standings.
Liverpool are outside the top eight and have lost two of their five European ties, although they have won on their last two away dates with Inter.
Score Prediction: Inter Milan 1-1 Liverpool
Monaco vs Galatasaray (Tuesday, 8pm)
Both of these teams are currently sat in the ‘middle eight’, with Galatasaray three points ahead of Monaco.
The hosts beat PSG at home at the end of last month but lost at the weekend, while Gala have lost two and drawn one of their last five matches in all competitions.
Score Prediction: Monaco 1-1 Galatasaray
PSV vs Atletico Madrid (Tuesday, 8pm)
Following a 4-1 win at Liverpool in Game Week Five, PSV are up to 15th and go into this clash having won the last five in all competitions.
Atletico Madrid lost 1-0 in Bilbao on Saturday, managing just two shots on target, and have also lost both Champions League games on the road this term.
Score Prediction: PSV 2-1 Atletico Madrid
Tottenham vs Slavia Prague (Tuesday, 8pm)
Tottenham have lost just one of their five Champions League games and that was at reigning European champions PSG, with a win at home likely to put them on the brink of the top eight.
Slavia Prague are still without a win, but they did claim 0-0 draws against Athletic Bilbao and Atalanta and will try to frustrate the hosts for long periods.
Score Prediction: Tottenham 2-0 Slavia Prague
Union Saint-Gilloise vs Marseille (Tuesday, 8pm)
These two teams are sat on six points after five games, with Marseille four places ahead of Union Saint-Gilloise due to goal difference.
The hosts have conceded 12 goals so far and Roberto De Zerbi’s visitors can take advantage.
Score Prediction: Union Saint-Gilloise 1-2 Marseille
Qarabag vs Ajax (Wednesday, 5.45pm)
Ajax are the only team still without a point in this season’s Champions League, with a trip to Azerbaijan looking set to extend that run.
Qarabag are unbeaten in their two European home ties, with one win and a draw and should be too strong for Ajax.
Score Prediction: Qarabag 2-0 Ajax
Villarreal vs Copenhagen (Wednesday, 5.45pm)
Villarreal have collected just one point from their first five European matches and now face a Copenhagen team who won their last match against Kairat.
The Yellow Submarines are third in LaLiga and this looks like the perfect opportunity to keep alive their hopes of making the play-offs.
Score Prediction: Villarreal 2-1 Copenhagen
Athletic Club vs Paris Saint-Germain (Wednesday, 8pm)
Athletic Club have collected just four points to date and have failed to score in their last two Champions League matches.
The LaLiga side now face the defending champions PSG, who have the best goalscoring record in the competition with 19 goals in five games.
Score Prediction: Athletic Club 1-3 Paris Saint-Germain
Bayer Leverkusen vs Newcastle (Wednesday, 8pm)
Back-to-back wins over Benfica and Manchester City have given Bayer Leverkusen a real chance of making the top eight.
They now face a Newcastle team who fell to a 2-1 defeat at Marseille in Game Week Five and have won just two of their nine away games this season.
Score Prediction: Bayer Leverkusen 2-1 Newcastle
Benfica vs Napoli (Wednesday, 8pm)
A 2-0 win over Ajax last time out kept alive Benfica’s hopes of finishing in the play-off places and they now face a Napoli team who have lost their two Champions League away games.
The visitors are top of Serie A following a 2-1 home win over Juventus at the weekend, but have not convinced in Europe since the injury to Kevin De Bruyne.
Score Prediction: Benfica 1-1 Napoli
Borussia Dortmund vs Bodo/Glimt (Wednesday, 8pm)
Three wins in their last four European matches has left Borussia Dortmund sat in sixth and a win on Wednesday can see them take a giant leap towards qualification.
Their Norwegian opponents, Bodo/Glimt, who finished second in their domestic league, have lost their last three Champions League matches.
Score Prediction: Borussia Dortmund 3-1 Bodo/Glimt
Club Brugge vs Arsenal (Wednesday, 8pm)
Club Brugge showed their attacking threat by scoring three goals against Barcelona in Game Week Four and could find the net against an Arsenal defence struck by injuries.
The Gunners have scored in their last 19 games in all competitions and should prove too strong even if they make changes.
Score Prediction: Club Brugge 1-2 Arsenal
Juventus vs Pafos (Wednesday, 8pm)
It took five matches for Juventus to claim their first European win of the campaign, with a 3-2 victory at Bodo/Glimt last time out.
Sunday’s defeat to Napoli was their first loss in their last nine in all competitions and they now face a Pafos team who are unbeaten in their last three in Europe (D2 W1)
Score Prediction: Juventus 2-0 Pafos
Real Madrid vs Manchester City (Wednesday, 8pm)
The game of the week sees two heavyweights clash at the Bernabeu, where Real Madrid are unbeaten in their last four meetings with Manchester City.
Last season’s clash in the Spanish capital finished in a 3-1 win for the hosts, with Kylian Mbappe scoring a hat-trick.
Score Prediction: Real Madrid 2-1 Manchester City
